The blonde beauty, who quit the kids' show last year after four years, giggled: "I feel liberated."
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Zoe, 29, a former Miss Northern Ireland who studied law, says: "I really hope Dancing On Ice shows people the complete and real me."
She also revealed she's dropped from a size 12 to an eight sliding around the rink with partner Matt Evers. "But my costume still leaves plenty on show," she added - proving she really has moved on from Blue Peter.
Zoe also spoke for the first time about her romance with Hollyoaks hunk Gerard McCarthy. Zoe said: "He's very understanding. He has his career and I have mine."
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