The five singers are each designing two dresses, some based on "biker chic" and the Hell's Angels.
A spokesman said: "Studs and rivet detailing will feature heavily, and themes from the 80s."
Frankie Sandford, Una Healy, Rochelle Wiseman, Vanessa White and Mollie King - who had a No2 hit with I Just Can't Get Enough - will sell their dresses through the Rare brand from June. They follow model- turned-designer Kate Moss.
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